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QUIMICA
(63.01)
TRABAJO PRACTICO N°: 3
DETERMINACION DE LA MASA MOLAR DEL MAGNESIO.
INTEGRANTES:
DATOS:
Volumen leído en la probeta = 0,043 dm3
Presión atmosférica = 1 Atm
Temperatura Ambiente = 18 ºC = 291 K
Presión parcial del vapor de agua a 18 ºC = 15,477 mmMg
Masa del Magnesio = 0,044 g
Altura de la columna de agua = 115 mm
Presion parcial del hidrogeno (pH2):
Patm = PH2 + Pvap. agua + Pcolumna de agua
hH2O . δH2O = hHg . δðg
hH2O = 11,5 cm
δH2O = 1 g/cm3
δðg = 13,6 g/cm3
hHg = hH2O . δH2O . 1
δðg
hHg = 8,45 mmHg
760 mmHg 1 Atm
8,45 mmHg x = 0,0111 Atm = hHg = Pcolumna de agua
Pvap. agua = 15,477 mmHg
760 mmHg 1 Atm
15,477 mmHg x = 0,0203 Atm = Pvap. agua
PH2 = Patm ð Pvap. agua ð Pcolumna de agua
PH2 = 0,986 Atm - 0,0203 Atm - 0,0111Atm
PH2 = 0,9686 Atm
VOLUMEN DE HIDROGENO (En CNPT )
Pcnpt . Vcnpt = P0 . V0
Tcnpt T0
Vcnpt = P0 . V0 . Tcnpt
T0 Pcnpt
Vcnpt = 0,9686 Atm . 0,043 dm3 . 273 K
291 K . 1 Atm
Vcnpt = 0,039 dm3
MASA MOLAR DEL MAGNASIO (DET. EXPERIMENTALMANTE)
Ec. Molecular.
Mg (s) + 2HCl (ac) → MgCl2 (ac) + H2 (g)
Él numero de moles de Magnesio es igual al numero de moles de Hidrogeno.
24,4 dm3 1 mol H2 (g)
0,039 dm3 x = 1,7443 mol H2 (g) = mol Mg
1,7443 mol Mg 0,044 g Mg
1 mol Mg x = 25,224 g Mg
ERRORES:
Error absoluto:
24,3 g ð 25,224 g = 0,924 g
Error relativo por ciento:
0,924 g . 100 = 3,80 %
24,3 g
7.-
Si se produce una fuga del gas obtenido:
Hay menos gas ð menos PH2 ð menos volumen ð menos masa de Mg ð Exceso.
Si el Mg utilizado contiene impurezas no atacables por el Cl (Aq):
Va a quedar Mg sin reaccionar ! va a haber menos H2 ! menos PH2 ! menos volumen ! menos masa de Mg ! Exceso.
Si se comete un error en la pesada de Mg:
Si pesamos mal el Mg nos va a dar una masa molar de este más grande de la que nos tiene que dar ! Exceso.
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Enviado por: | Julian A. Lavado |
Idioma: | castellano |
País: | España |